Mid infrared solid-state lasers are made possible by using innovative low phonon energy materials. Until recently, such lasers were not feasible because they characteristically had a short upper laser level lifetime. Thus, they were unable to store much energy and accumulate a high laser gain. By using a low phonon energy laser materials, nonradiative losses from the upper laser level can be minimized. In turn, the upper laser manifold lifetime increases, thus the laser gain. An innovative laser design can also be used with mid infrared lasers to provide enhanced detection capabilities. As a principle of parsimony with provided funding it is wise to choose the best candidates to examine first. These would be Pr and Dy for targeting CH4 (methane) and CO. Using earlier spectroscopic studies, lasers can be designed to operate on MIR transitions in low phonon materials. If successful, MIR lasers can be further developed for a variety of Ln3+ ions in low phonon hosts to address various MIR spectral regions. The impact is clear and in the MIR region, broad spectral coverage buys access to chemical "fingerprints," where molecules can be detected and distinguished with great sensitivity. In fact, the region of the MIR from 3 to 10 μm has distinct 'Fingerprint Regions' of interest for remote sensing, specifically 3-5 & 7-10 µm.
More »The main objective is to demonstrate mid infrared (MIR) lasers for active remote sensing applications. Two factors work in favor of such instruments: (1) MIR atmospheric absorption bands in the 2-10 μm region are very wide and consist of large numbers of narrow and relatively equally spaced spectral lines and (2) MIR emission bands of lanthanide (Ln3+) are also wide, providing the tunable lasers to address atmospheric absorption. For example, Pr (praseodymium) lasers operating around 2.5 and 5 μm can target CO (carbon monoxide) and N2O (nitrous oxide). Previous work done at Langley indicate lanthanide series elements, Pr, Dy, Er, and Ho can be incorporated in low phonon hosts like LaF3 and KPb2Cl5 to produce MIR lasers. Laser demonstrations in the MIR remain in their infancy, with just a few examples to date. Such efforts can be of substantial benefit to NASA in exploring the MIR spectral ranges, rich in many atmospheric molecular gasses. Regarding detectors on the remote sensing measurement end, the field continues to develop in parallel with MIR lasers. APD's (Avalanche Photo Diodes) based on narrow-gap II-V semiconductors are being developed in the 2-5 μm range. New materials like HgTe have exhibited room temperature photo response > 5 μm.
More »Organizations Performing Work | Role | Type | Location |
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Langley Research Center (LaRC) | Lead Organization | NASA Center | Hampton, Virginia |
Hampton University | Supporting Organization |
Academia
Historically Black Colleges and Universities (HBCU)
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Hampton, Virginia |