400 Wh/kg Secondary Battery, Phase I

Summary Lithium-ion battery technology will not provide significant breakthroughs beyond 200 Wh/kg. It will not provide adequate specific energy and cycle life for Earth Science missions. It will not enable the United States to reestablish its position of strategic technical advantage in portable energy storage. However, the next generation of secondary Li batteries is being developed in the US. It is based on lithium metal anodes and sulfur containing liquid cathodes. The sulfur-based cathode delivers a theoretical specific energy of 2450 Wh/kg, more than any other known cathode material of secondary cell. The Li-S battery needs advanced technology for improved stabilization of the Li anode in the corrosive environment of the liquid sulfur cathode. We propose a novel application of modern rocket fuel chemistry to create a self-healing, solid-electrolyte interface (SEI) layer. Li-S cells equipped with this robust passivation will stably perform at 400 Wh/kg level for ~ 300 cycles. At 200 Wh/kg a cycle life of ~ 1000 cycles is expected. The good low temperature performance and excellent rate capability features of Li-S cell will remain intact. These features are the next leap toward the advanced energy storage technologies required for Earth science observation platforms. More »