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Pursue molecular- and nano-based catalysts to attach and activate CO2 molecules to release dioxygen (O2) after the application of external energy. Our approach seeks to prove that molecular catalysis with electrochemistry is more efficient than high temperature to generate O2.
","benefits":"Generating O2 from CO2 under benign conditions could provide next generation technology for in situ resource utilization in potential manned missions on Mars, ISS, and other planetary environments. The system in this work could potentially be leveraged to produce fuels, fertilizers, or other species for ISRU applications. The CO2 conversion to O2 technology could provide an effective approach to recycle CO2 from the terrestrial atmosphere and offers great promise for climate control. The system shows promise and is currently at TRL 2.
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","parentProgram":{"ableToSelect":false,"isActive":true,"description":"Catalyst is a portfolio of early stage programs that specialize in different innovation constituencies and mechanisms to push the state of the art in aerospace technology development","programId":92327,"responsibleMd":{"canUserEdit":false,"locationEdit":false,"organizationRolePretty":"","organizationTypePretty":""},"title":"Catalyst","manageGaps":false,"acronymOrTitle":"Catalyst"},"parentProgramId":92327,"programId":64,"responsibleMd":{"canUserEdit":false,"locationEdit":false,"organizationRolePretty":"","organizationTypePretty":""},"stockImageFileId":36643,"title":"Center Innovation Fund","manageGaps":false,"acronymOrTitle":"CIF"},"parentProgramId":64,"programId":164,"responsibleMd":{"organizationId":4875,"organizationName":"Space Technology Mission Directorate","acronym":"STMD","organizationType":"NASA_Mission_Directorate","canUserEdit":false,"locationEdit":false,"organizationRolePretty":"","organizationTypePretty":"NASA Mission Directorate"},"responsibleMdOffice":4875,"stockImageFileId":36651,"title":"Center Innovation Fund: JPL CIF","manageGaps":false,"acronymOrTitle":"JPL CIF"},"description":"Two key technical challenges will be addressed: Construction of binuclear-CO2 complexes with CO2-CO2 spatially close enough to each other and activation of binuclear-CO2 complexes to release oxygen by electrochemistry (oxidation or reduction). Our goal is to pursue a molecular-based catalyst to attach and activate multiple CO2 molecules to release O2 after the application of external energy. The CO2 conversion to O2 technology would provide an effective approach to recycle CO2 from the terrestrial atmosphere and offer great promise for climate control. In addition, binuclear complex systems could convert CO2 to hydrocarbons with two or more carbon atoms and open a route for the production of fuels from the vast CO2 supply. This technology would change the future energy landscape and mark the beginning of a green energy age.","benefits":"Generating O2 from CO2 under benign conditions could provide next generation technology for in situ resource utilization in potential manned missions on Mars, ISS, and other planetary environments. The system in this work could potentially be leveraged to produce fuels, fertilizers, or other species for ISRU applications. The CO2 conversion to O2 technology could provide an effective approach to recycle CO2 from the terrestrial atmosphere and offers great promise for climate control. The system shows promise and is currently at TRL 2.","releaseStatus":"Released","status":"Completed","destinationType":[],"trlBegin":1,"trlCurrent":2,"trlEnd":2,"favorited":false,"detailedFunding":false,"programContacts":[{"contactId":155484,"canUserEdit":false,"firstName":"Fred","lastName":"Hadaegh","fullName":"Fred Y Hadaegh","fullNameInverted":"Hadaegh, Fred Y","middleInitial":"Y","email":"fred.y.hadaegh@jpl.nasa.gov","receiveEmail":"Subscribed_User","programContactRole":"Program_Manager","programContactId":112,"programId":164,"programContactRolePretty":"Program Manager","projectContactRolePretty":""},{"contactId":159179,"canUserEdit":false,"firstName":"Gary","lastName":"Fleming","fullName":"Gary A Fleming","fullNameInverted":"Fleming, Gary A","middleInitial":"A","email":"gary.a.fleming@nasa.gov","receiveEmail":"Subscribed_User","programContactRole":"Program_Manager","programContactId":241,"programId":164,"programContactRolePretty":"Program Manager","projectContactRolePretty":""},{"contactId":233104,"canUserEdit":false,"firstName":"John","lastName":"Nelson","fullName":"John C Nelson","fullNameInverted":"Nelson, John C","middleInitial":"C","email":"john.c.nelson@nasa.gov","receiveEmail":"Subscribed_User","programContactRole":"Program_Director","programContactId":238,"programId":164,"programContactRolePretty":"Program Director","projectContactRolePretty":""}],"endDateString":"Jul 2017","startDateString":"Oct 2016"},"technologyOutcomePartner":"Other","technologyOutcomeDate":"2017-10-01","technologyOutcomePath":"Advanced_From","infoText":"Advanced from another project within the program","infoTextExtra":"Another project within the program (In Situ Oxygen Generation from CO2 under Benign Conditions, Year 1)","isIndirect":true,"technologyOutcomePathPretty":"Advanced From","technologyOutcomeRationalePretty":"","infusionPretty":"","isBiDirectional":true,"technologyOutcomeDateString":"Oct 2017","technologyOutcomeDateFullString":"October 2017","technologyOutcomePartnerPretty":"Other"}],"libraryItems":[{"files":[],"libraryItemId":367736,"title":"Project Website","libraryItemType":"Link","url":"https://www.nasa.gov/directorates/spacetech/home/index.html","projectId":93948,"internalOnly":false,"publishedDateString":"","entryDateString":"01/22/25 01:10 AM","libraryItemTypePretty":"Link","modifiedDateString":"10/25/24 02:23 PM"}],"states":[{"abbreviation":"CA","country":{"abbreviation":"US","countryId":236,"name":"United States"},"countryId":236,"name":"California","stateTerritoryId":59,"isTerritory":false}],"endDateString":"Sep 2018","startDateString":"Oct 2017"}}